2 edition of Allyl alcohol. found in the catalog.
Shell Chemical Corporation.
in San Francisco
Written in English
|Series||Its Technical Publication -- SC, 46-32, Technical publication (Shell Chemical Corporation) -- SC 46-32.|
|Contributions||Shell Development Company.|
|The Physical Object|
|Pagination||95 p. :|
|Number of Pages||95|
From glycerol to allyl alcohol: iron oxide catalyzed dehydration and consecutive hydrogen transfer† Yong Liu, a Harun Tüysüz, a Chun-Jiang Jia, a Manfred Schwickardi, a Roberto Rinaldi, a An-Hui Lu, a Wolfgang Schmidt a and Ferdi Schüth * aCited by: Allyl alcohol definition: a colourless pungent poisonous liquid used in the manufacture of resins, plasticizers, | Meaning, pronunciation, translations and examples.
allyl alcohol: 1 n an unsaturated primary alcohol present in wood spirit; use to make resins and plasticizers and pharmaceuticals Synonyms: propenyl alcohol Type of: alcohol any of a series of volatile hydroxyl compounds that are made from hydrocarbons by distillation. An allyl group is a substituent with the structural formula H 2 C=CH−CH 2 R, where R is the rest of the molecule. It consists of a methylene bridge (−CH 2 −) attached to a vinyl group (−CH=CH 2). The name is derived from the Latin word for garlic, Allium , Theodor Wertheim isolated an allyl derivative from garlic oil and named it "Schwefelallyl".
Download Citation | Allyl Alcohol | C3H6O1 (MW ) InChI=1S/C3H6O/c/h2,4H,1,3H2 XXROGKLTLUQVRX-UHFFFAOYSA-N Key: common building block and allylation. Allyl alcohol, C 3 H 5 OH, earlier came into prominence as a toxic substance through the belief that its presence in wood alcohol (methyl alcohol) as an impurity largely accounted for the toxicity of the latter substance. Allyl alcohol may be present in natural methyl alcohol in such quantities as per cent. This attempt to shift the major responsibility for Cited by:
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Allyl alcohol is a propenol in which the C=C bond connects C-2 and C It is has been found in garlic (Allium sativum). Formerly used as a herbicide for the control of various grass and weed seeds. It has a role as an insecticide, a herbicide, an antibacterial agent, a fungicide and a plant metabolite.
It is a primary allylic alcohol and a. Allylic alcohol was obtained very efficiently from the alcohol after a three-step sequence involving an oxidation of the alcohol using IBX, a Wittig olefination and the reduction of the resulting (E)-α,β-unsaturated ester (Scheme 37).
then underwent a Sharpless asymmetric epoxidation with (−)-diethyl tartrate to provide the epoxy alcohol in more than 98% e.e. Allyl acetate's use in the production of allyl alcohol may result in its release to the environment through various waste streams.
If released to air, a vapor pressure of mm Hg at 20 °C indicates allyl acetate will exist solely as a vapor in the ambient atmosphere. Allyl alcohols are not appropriate substrates for selective hydroformylation with cobalt catalysts.
Allyl alcohol reacts to give 4-hydroxybutanal and 2-methylhydroxypropanal and the corresponding 1,3-dioxane and tetrahydrofuran derivatives in less than 30% yield with Allyl alcohol.
book tetracarbonyl. allyl alcohol[′aləl ′alkə‚hȯl] (organic chemistry) CH2CHCH2OH Colorless, pungent liquid, boiling at 96°C; soluble in water; made from allyl chloride by hydrolysis.
Allyl Alcohol an elementary unsaturated alcohol; CH2=CH−CH2OH. It is a colorless liquid with a sharp odor It boils at °C, and its density is kg/m3; it mixes in any.
Book: Additional Physical Format: Online version: Shell Chemical Corporation. Allyl alcohol. San Francisco  (OCoLC) Document Type: Book: All Authors / Contributors: Shell Chemical Corporation.; Shell Development Company.
OCLC Number: Notes: "Written by the staff of Shell Development Company." Description: 95 pages. Search results for allyl alcohol at Sigma-Aldrich. Compare Products: Select up to 4 products. *Please select more than one item to compare. The toxicity of allyl alcohol. Acute and chronic toxicity. AMA Arch Ind Health Izmerov NF, Sanotsky IV, Sidorov KK .
Toxicometric parameters of industrial toxic chemicals under single exposure. Moscow, Russia: Centre of International Projects, GKNT, p.
McCord CP . The toxicity of allyl alcohol. JAMA 98(26) Allyl alcohol is an industrially important olefinic alcohol. It is the raw material for the synthesis of a wide range of allylic derivatives such as allyl diglycol carbonate, allyl glycidyl ether, 1,4-butanediol, poly (styrene-allyl alcohol), etc.
These derivatives find application as lens, coupling agents, plasticizers, crosslinking agents and. Allyl Alcohol Hardcover – January 1, by Author Unknown (Author) See all formats and editions Hide other formats and editions.
Price New from Used from Hardcover "Please retry" $ — $ Hardcover $ 5 Author: Author Unknown. Allyl Alcohol (CAS #) Information for the Public What is allyl alcohol. Allyl alcohol is a toxic, colorless liquid.
It is an extremely hazardous substance, can cause severe irritation and must be handled with extreme caution. In small amounts, the odor is alcohol-like. In larger amounts, the odor is pungent and mustard-like. ALLYL ALCOHOL Hardcover – by (Author) See all formats and editions Hide other formats and editions.
Price New from Used from Hardcover, "Please retry" — — — Hardcover Author: (chemistry). Allyl alcohol is a colorless liquid with a pungent, mustard-like odor. The most important adverse effects of occupational exposures to allyl alcohol are upper-respiratory-tract irritation and burns of the eyes.
In a controlled human sensory response study (Dunlap, Kodama, Wellington et al. /Ex. ), a five-minute exposure to 25 ppm. Allyl chloride is the organic compound with the formula C H 2 =CHCH 2 colorless liquid is insoluble in water but soluble in common organic solvents.
It is mainly converted to epichlorohydrin, used in the production of is a chlorinated derivative of is an alkylating agent, which makes it both useful and hazardous to ance: Colorless, brown, yellow, or purple liquid.
E-Mail Address. Password. Forgotten Password. Remember Me. Allyl alcohol. Brief Profile - Last updated: 08/04/ Print. Sub. description Substance description Substance description. The ’Substance description’ gives an overview of the main substance identifiers, substance classification, on-going regulatory activities, main uses of the substance and which registrants manufacture and/or import the.
ALLYL ALCOHOL presents a dangerous fire and explosion hazard when exposed to heat, flame, or oxidizing agents. Reacts violently or explosively with sulfuric acid, strong bases. Reacts violently with 2,4,6-trichloro-1,3,5-triazine and 2,4,6-tris(bromoamino)-1,3,5-triazine.
Allyl alcohol. Allyl alcohol (IUPAC name: propenol) is an organic compound with the structural formula CH2=CHCH2OH. Like many alcohols, it is a water-soluble, colourless liquid. It is more toxic than typical small alcohols.
Allyl alcohol is used as a raw material for the production of glycerol, but is also used as a precursor to many. INTRODUCTION. Allyl alcohol is a colorless liquid that is a potent sensory irritant.
The chemical has a pungent, mustard-like odor, with a reported odor-recognition concentration of ppm (Dunlap et al. ; HSDB ) and odor-detection threshold of ppm ().Primarily used in the production of allyl esters for use in resins and plasticizers, allyl alcohol is also used. To begin to assess the importance of thrombin in the LPS enhancement of allyl alcohol hepatotoxicity, rats were treated with heparin ( U/kg) 1 h before LPS; this dosing regimen reduces liver injury from a larger dose of LPS (Hewett and Roth, ).
Heparin is an anticoagulant that enhances the binding of antithrombin III to thrombin Cited by: 9. The results as in Figure 6 showed that the extraction efficiency of the solvent trichloromethane was the highest for dimethylamine, allyldimethylamine, allyl chloride, allyl alcohol, and allyl aldehyde with the values of %, %, %, %, and %, respectively.Define allyl alcohol.
allyl alcohol synonyms, allyl alcohol pronunciation, allyl alcohol translation, English dictionary definition of allyl alcohol.
n a colourless pungent poisonous liquid used in the manufacture of resins, plasticizers, and other organic chemicals.1. Drug Metabol Drug Interact.
;7(4) Aspects of allyl alcohol toxicity. Atzori L(1), Dore M, Congiu L. Author information: (1)Istituto di Patologia Generale, Universita'degli Studi di Cagliari, Italy.
The more recent experimental works on the chemistry, industrial uses and general toxicity (with particular reference to liver cell injury) of allyl alcohol (AA) have been briefly Cited by: